Radical–anion coupling through reagent design: hydroxylation of aryl halides

Author:

Greener Andrew J.1ORCID,Ubysz Patrycja1,Owens-Ward Will1,Smith George1,Ocaña Ivan1,Whitwood Adrian C.1ORCID,Chechik Victor1,James Michael J.1ORCID

Affiliation:

1. Department of Chemistry, University of York, Heslington, York, YO10 5DD, UK

Abstract

The design and development of an oxime-based hydroxylation reagent, which can chemoselectively convert aryl halides (X = F, Cl, Br, I) into phenols under operationally simple, transition-metal-free conditions is described.

Funder

University of York

Leverhulme Trust

Royal Society

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

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