Inclusion complexes of Cethyl-2-methylresorcinarene and pyridine N-oxides: breaking the C–I⋯−O–N+ halogen bond by host–guest complexation-Reference-Cited by-同舟云学术

Inclusion complexes of Cethyl-2-methylresorcinarene and pyridine N-oxides: breaking the C–I⋯−O–N+ halogen bond by host–guest complexation

Published:2016 Issue:5 Volume:18 Page:793-799
ISSN:1466-8033
Container-title:CrystEngComm
language:en
Short-container-title:CrystEngComm

Author:

Puttreddy Rakesh¹²³⁴,Beyeh Ngong Kodiah¹²³⁴⁵,Rissanen Kari¹²³⁴

Affiliation:

1. Department of Chemistry

2. University of Jyvaskyla

3. Nanoscience Center

4. , Finland

5. Department of Applied Physics

Abstract

C_ethyl-2-Methylresorcinarene and aromatic N-oxides manifest host–guest chemistry by C–H⋯π interactions and halogen bonding; the C–I⋯⁻O–N⁺ halogen bond with 2-iodopyridine N-oxide is broken by the in-cavity C–I⋯π interactions.

Funder

Luonnontieteiden ja Tekniikan Tutkimuksen Toimikunta

Publisher

Royal Society of Chemistry (RSC)

Subject

Condensed Matter Physics,General Materials Science,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/CE/C5CE02354H

Reference75 articles.

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3. Very Large Container Molecules

4. Anion-sealed single-molecule capsulesElectronic supplementary information (ESI) available: Experimental details. See http://www.rsc.org/suppdata/cc/b3/b301511d/

5. Organization of the interior of molecular capsules by hydrogen bonding

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