Metal-free direct C–H phosphonation of N-heterocycles with diphenylphosphine oxides under mild conditions-Reference-Cited by-同舟云学术

Metal-free direct C–H phosphonation of N-heterocycles with diphenylphosphine oxides under mild conditions

Published:2023 Issue:14 Volume:25 Page:5721-5726
ISSN:1463-9262
Container-title:Green Chemistry
language:en
Short-container-title:Green Chem.

Author:

Cai Zhao-Nan¹,Han Ya-Ping¹^ORCID,Zhang Yuecheng¹^ORCID,Zhang Hong-Yu¹^ORCID,Zhao Jiquan¹^ORCID,Yang Shang-Dong²^ORCID

Affiliation:

1. School of Chemical Engineering and Technology, Hebei Provincial Key Lab of Green Chemical Technology & High Efficient Energy Saving, Tianjin Key Laboratory of Chemical Process Safety, Hebei University of Technology, Tianjin 300130, P. R. China

2. State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou 730000, P. R. China

Abstract

Herein, metal-free phosphonation of N-heterocycles with diphenylphosphine oxides, promoted by 1,5-diazabicyclo[5,4,0]undec-5-ene utilizing air as a green oxidant in dimethyl carbonate as an eco-friendly solvent at room temperature, is presented.

Funder

Natural Science Foundation of Hebei Province

Hubei Provincial Central Guidance Local Science and Technology Development Project

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Environmental Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/GC/D3GC01251D

Reference61 articles.

1. A Mild and Efficient Copper-Mediated N-Arylation of 6-Azauracil with Corresponding Boronic Acids and their Antibacterial Activity

2. Design and Synthesis of Potent and Multifunctional Aldose Reductase Inhibitors Based on Quinoxalinones