Sodium mediated deprotonative borylation of arenes using sterically demanding B(CH2SiMe3)3: unlocking polybasic behaviour and competing lateral borane sodiation-Reference-Cited by-同舟云学术

Sodium mediated deprotonative borylation of arenes using sterically demanding B(CH₂SiMe₃)₃: unlocking polybasic behaviour and competing lateral borane sodiation

Published:2023 Issue:24 Volume:14 Page:6538-6545
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Tortajada Andreu¹^ORCID,Bole Leonie J.¹,Mu Manting²,Stanford Martin¹^ORCID,Peñas-Defrutos Marconi N.²³^ORCID,García-Melchor Max²^ORCID,Hevia Eva¹^ORCID

Affiliation:

1. Department für Chemie und Biochemie, Universität Bern, Freiestrasse 3, 3012 Bern, Switzerland

2. School of Chemistry, CRANN and AMBER Research Centres, Trinity College Dublin, College Green, Dublin 2, Ireland

3. IU CINQUIMA/Química Inorgánica, Facultad de Ciencias, Universidad de Valladolid, 47071-Valladolid, Spain

Abstract

Mechanistic studies on sodium-mediated borylation of arenes, uncover a unique polybasic behaviour for the formal borylation of two equivalents of the relevant arene as well as the competing formation of a borata-alkene complexes.

Funder

Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung

Irish Research Council

University of Bern

Universidad de Valladolid

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/SC/D3SC01705B

Reference52 articles.