Simultaneous enhancement of thermally activated delayed fluorescence and photoluminescence quantum yield via homoconjugation

Author:

Montanaro Stephanie1,Pander Piotr23ORCID,Mistry Jai-Ram1ORCID,Elsegood Mark R. J.1ORCID,Teat Simon J.4ORCID,Bond Andrew D.5ORCID,Wright Iain A.1ORCID,Congrave Daniel G.5ORCID,Etherington Marc K.6ORCID

Affiliation:

1. Department of Chemistry, Loughborough University, Epinal Way, LE11 3TU, UK

2. Department of Physics, Durham University, South Road, Durham, DH1 3LE, UK

3. Centre for Organic and Nanohybrid Electronics, Silesian University of Technology, Konarskiego 22B, 44-100 Gliwice, Poland

4. Advanced Light Source, Lawrence Berkeley National Laboratory, Cyclotron Road, Berkeley, CA, 94720, USA

5. Yusuf Hamied Department of Chemistry, Cambridge, CB2 1EW, UK

6. Department of Mathematics, Physics and Electrical Engineering, Northumbria University, Ellison Place, Newcastle upon Tyne, NE1 8ST, UK

Abstract

A new iptycene unequivocally validates homoconjugation as a viable strategy to simultaneously enhance TADF reverse intersystem crossing and radiative decay.

Funder

Loughborough University

Engineering and Physical Sciences Research Council

Royal Society of Chemistry

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry

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