Guanidine as inexpensive dual function ligand and reducing agent for ATRP of methacrylates
Author:
Affiliation:
1. CEMMPRE
2. Centre for Mechanical Engineering
3. Materials and Processes
4. Department of Chemical Engineering
5. University of Coimbra
6. Department of Chemical Sciences
7. University of Padova
8. 35131 Padova
9. Italy
Abstract
N,N,N′,N′-Tetramethyl guanidine, an inexpensive and commercially available organic base, is used for the first time as ligand without any chemical modification for the supplemental activator and reducing agent atom transfer radical polymerization.
Funder
Conselho Nacional de Desenvolvimento Científico e Tecnológico
European Regional Development Fund
Fundação para a Ciência e a Tecnologia
Publisher
Royal Society of Chemistry (RSC)
Subject
Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering
Link
http://pubs.rsc.org/en/content/articlepdf/2019/PY/C9PY00925F
Reference35 articles.
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3. "Living"/Controlled Radical Polymerization. Transition-Metal-Catalyzed Atom Transfer Radical Polymerization in the Presence of a Conventional Radical Initiator
4. Ambient temperature rapid SARA ATRP of acrylates and methacrylates in alcohol–water solutions mediated by a mixed sulfite/Cu(ii)Br2 catalytic system
5. Grafting from Surfaces for “Everyone”: ARGET ATRP in the Presence of Air
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