[Br4F21] – a unique molecular tetrahedral interhalogen ion containing a μ4-bridging fluorine atom surrounded by BrF5 molecules

Author:

Möbs Martin1,Graubner Tim1,Karttunen Antti J.2,Kraus Florian1ORCID

Affiliation:

1. Anorganische Chemie, Fluorchemie, Philipps-Universität Marburg, Hans-Meerwein-Str. 4, 35032 Marburg, Germany

2. Department of Chemistry and Materials Science, Aalto University, 00076 Espoo, Finland

Abstract

The [(μ4-F)(BrF5)4] anion in [NMe4][Br4F21]·BrF5 is the first example of F atoms bridging μ4-like outside ionic solids or [F(HF)4] anions.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Reference33 articles.

1. E. W.Lawless and I. C.Smith , Inorganic High-Energy Oxidizers - Synthesis, Structure, and Properties , Marcel Dekker, Inc. , New York , 1968

2. W. I.Bailey and A. J.Woytek , in Kirk-Othmer Encyclopedia of Chemical Technology , John Wiley & Sons, Inc. , 2000

3. �ber Fluoro ? onium-Verbindungen. I

4. Halogen and interhalogen cations

5. K. O.Christe , in XXIVth International Congress of Pure and Applied Chemistry , Butterworth , London , 1974 , pp. 115–141

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