Exploring a new short-wavelength nonlinear optical fluoride material featuring unprecedented polar cis-[Zr6F34]10− clusters-Reference-Cited by-同舟云学术

Exploring a new short-wavelength nonlinear optical fluoride material featuring unprecedented polar cis-[Zr₆F₃₄]¹⁰⁻ clusters

Published:2024 Issue:8 Volume:15 Page:2883-2888
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Yan Mei¹,Tang Ru-Ling¹^ORCID,Yao Wen-Dong¹,Liu Wenlong¹^ORCID,Guo Sheng-Ping¹^ORCID

Affiliation:

1. School of Chemistry and Chemical Engineering, Yangzhou University, 180 Siwangting Road, Yangzhou 225002, P. R. China

Abstract

The new zirconium fluoride, K3Ba2Zr6F31, is reported, featuring unprecedented acentric cis-[Zr6F34]10− clusters composed of ZrF8 units, which display a moderate second-harmonic generation response (0.5 × KH2PO4) and short UV cutoff edge (below 200 nm).

Funder

National Natural Science Foundation of China

Graduate Research and Innovation Projects of Jiangsu Province

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/SC/D3SC06683E

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