The systematic influence of solvent on the conformational features of furanosides-Reference-Cited by-同舟云学术

The systematic influence of solvent on the conformational features of furanosides

Published:2019 Issue:9 Volume:17 Page:2479-2485
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Gaweda Karolina¹²³⁴,Plazinski Wojciech¹²³⁴^ORCID

Affiliation:

1. Jerzy Haber Institute of Catalysis and Surface Chemistry

2. Polish Academy of Sciences

3. 30-239 Cracow

4. Poland

Abstract

The conformational properties of furanosides are systematically affected by polar solvent which rearranges average partial atomic charges on ring atoms and shifts conformational equilibrium toward specific ring shapes.

Funder

Narodowe Centrum Nauki

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/OB/C9OB00043G

Reference55 articles.

1. Extreme conformational flexibility of the furanose ring in DNA and RNA

2. How do the gauche and anomeric effects drive the pseudorotational equilibrium of the pentofuranose moiety of nucleosides?

3. How Does the 2'-Hydroxy Group Drive the Pseudorotational Equilibrium in Nucleoside and Nucleotide by the Tuning of the 3'-Gauche Effect?

4. Conformations of methyl 2'-deoxy-.alpha.-D-ribofuranoside and methyl 2'-deoxy-.beta.-D-ribofuranoside. A proton magnetic resonance spectroscopy and molecular mechanics study

5. How flexible is the furanose ring? 2. An updated potential energy estimate

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