Formic acid catalyzed isomerization and adduct formation of an isoprene-derived Criegee intermediate: experiment and theory

Author:

Vansco Michael F.1234ORCID,Caravan Rebecca L.56784ORCID,Pandit Shubhrangshu12349ORCID,Zuraski Kristen56784ORCID,Winiberg Frank A. F.678410ORCID,Au Kendrew111213144,Bhagde Trisha1234ORCID,Trongsiriwat Nisalak1234,Walsh Patrick J.1234ORCID,Osborn David L.111213144ORCID,Percival Carl J.6784ORCID,Klippenstein Stephen J.1516174ORCID,Taatjes Craig A.111213144ORCID,Lester Marsha I.1234ORCID

Affiliation:

1. Department of Chemistry

2. University of Pennsylvania

3. Philadelphia

4. USA

5. NASA Postdoctoral Program Fellow

6. NASA Jet Propulsion Laboratory

7. California Institute of Technology

8. Pasadena

9. Department of Chemistry and Biochemistry

10. Division of Chemistry and Chemical Engineering

11. Combustion Research Facility

12. Mailstop 9055

13. Sandia National Laboratories

14. Livermore

15. Chemical Sciences and Engineering Division

16. Argonne National Laboratory

17. Lemont

Abstract

Investigation of key reaction pathways for an isoprene-derived Criegee intermediate with formic acid: acid catalyzed isomerization and adduct formation.

Funder

National Nuclear Security Administration

Jet Propulsion Laboratory

Division of Chemistry

Basic Energy Sciences

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

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