Pre-inverse-crowns: synthetic, structural and reactivity studies of alkali metal magnesiates primed for inverse crown formation-Reference-Cited by-同舟云学术

Pre-inverse-crowns: synthetic, structural and reactivity studies of alkali metal magnesiates primed for inverse crown formation

Published:2014 Issue:2 Volume:5 Page:771-781
ISSN:2041-6520
Container-title:Chem. Sci.
language:en
Short-container-title:Chem. Sci.

Author:

Martínez-Martínez A. J.¹²³⁴,Armstrong D. R.¹²³⁴,Conway B.¹²³⁴,Fleming B. J.¹²³⁴,Klett J.¹²³⁴,Kennedy A. R.¹²³⁴,Mulvey R. E.¹²³⁴,Robertson S. D.¹²³⁴,O'Hara C. T.¹²³⁴

Affiliation:

1. WestCHEM

2. Department of Pure and Applied Chemistry

3. University of Strathclyde

4. Glasgow, UK

Abstract

The synthesis, structure and reactivity of donor-free sodium and potassium magnesiates are assessed culminating in the unique 1,4-dimetallation of naphthalene.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2014/SC/C3SC52816B

Reference169 articles.

1. Mixed AggregAte (MAA): A Single Concept for All Dipolar Organometallic Aggregates. 2. Syntheses and Reactivities of Homo/HeteroMAAs

2. Cationic, Neutral, and Anionic Allyl Magnesium Compounds: Unprecedented Ligand Conformations and Reactivity Toward Unsaturated Hydrocarbons

3. Two-, three- and four-component coupling to form isoquinolones based on directed metalation

4. Synthesis and structural elucidation of a rare example of a tris(amido) potassium magnesiate

5. Synthesis, Structural Elucidation, and Diffusion-Ordered NMR Studies of Homoleptic Alkyllithium Magnesiates: Donor-Controlled Structural Variations in Mixed-Metal Chemistry

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