Structural effects of soft nanoparticulate ligands on trace metal complexation thermodynamics

Author:

Rotureau Elise12345ORCID,Waldvogel Yves12345,Pinheiro José P.12345,Farinha José Paulo S.678910ORCID,Bihannic Isabelle12345,Présent Romain M.12345,Duval Jérôme F. L.12345

Affiliation:

1. CNRS

2. LIEC (Laboratoire Interdisciplinaire des Environnements Continentaux)

3. UMR 7360

4. Vandoeuvre-lès-Nancy F-54501

5. France

6. Centro de Quimica Fisica Molecular and IN-Institute of Nanoscience and Nanotechnology

7. Instituto Superior Tecnico

8. University of Lisbon

9. 1049-001 Lisboa

10. Portugal

Abstract

In this work, we investigate the impacts of temperature- and salinity-mediated modifications of the shell structure of polymeric ligand nanoparticles on the thermodynamics of divalent metal ions Cd(ii)-complexation.

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Reference55 articles.

1. J. Buffle , Complexation Reactions in Aquatic Systems: an Analytical Approach, Ellis Horwood series, Chichester, UK, 1988

2. M. Filella , in Environmental colloids and particles: behaviour, separation and characterisation, ed. K. J. Wilkinson and J. R. Lead, John Wiley & Sons, Chichester, West Sussex, UK, 2007, pp. 17–93

3. G. E. Batley , in Trace Element Speciation in Surface Waters and Its Ecological Implications, ed. G. G. Leppard, Springer, US, 1983, pp. 17–36

4. Estuarine trace metal distributions in Galveston Bay: importance of colloidal forms in the speciation of the dissolved phase

5. Chemodynamics of Aquatic Metal Complexes: From Small Ligands to Colloids

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