Preparation of monopodal and bipodal aluminum surface species by selective protonolysis of highly reactive [AlH3(NMe2Et)] on silica-Reference-Cited by-同舟云学术

Preparation of monopodal and bipodal aluminum surface species by selective protonolysis of highly reactive [AlH3(NMe2Et)] on silica

Published:2017 Issue:35 Volume:46 Page:11547-11551
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Sauter D. W.¹²³⁴⁵,Chiari V.¹²³⁴⁵,Aykac N.⁶⁷⁸⁹¹⁰,Bouaouli S.⁶⁷⁸⁹¹⁰,Perrin L.⁶⁷⁸⁹¹⁰,Delevoye L.¹¹¹²¹³¹⁴¹⁵,Gauvin R. M.¹¹¹²¹³¹⁴¹⁵^ORCID,Szeto K. C.¹²³⁴⁵,Boisson C.¹²³⁴⁵^ORCID,Taoufik M.¹²³⁴⁵

Affiliation:

1. Université de Lyon

2. Univ. Lyon 1

3. CPE Lyon

4. CNRS UMR 5265

5. Laboratoire de Chimie Catalyse Polymères et Procédés (C2P2)

6. Université Lyon 1

7. CNRS UMR 5246

8. Institut de Chimie et Biochimie Moléculaires et Supramoléculaires

9. Villeurbanne

10. France

11. Univ. Lille

12. CNRS

13. Centrale Lille

14. ENSCL

15. Univ. Artois

Abstract

The reaction of [AlH₃(NMe₂Et)] with silica treated at 200 °C leads to a well-defined bipodal aluminum hydride while with silica treated at 700 °C a mixture of mono- and bi-podal aluminum hydrides is obtained.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/DT/C7DT02575K

Reference25 articles.

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3. “Bound but Not Gagged”Immobilizing Single-Site α-Olefin Polymerization Catalysts

4. Preparation and characterization of metallacalixarenes anchored to a mesoporous silica SBA-15 LP as potential catalysts

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