Rational design and syntheses of aniline-based diradical dications: isolable congeners of quinodimethane diradicals

Author:

Fang Yong12345,Sun Qiang12345,Chen Xiaoyu12345,Qiu Yunfan12345,Chen Chao12345,Wang Lei12345,Zhao Yue12345ORCID,Su Yuanting678910,Li Tao1112131410,Zhang Li15161710,Wang Xinping12345ORCID

Affiliation:

1. State Key Laboratory of Coordination Chemistry

2. Jiangsu Key Laboratory of Advanced Organic Materials

3. School of Chemistry and Chemical Engineering

4. Collaborative Innovation Center of Advanced Microstructures

5. Nanjing University

6. College of Chemistry

7. Chemical Engineering and Materials Science

8. Soochow University

9. Suzhou 215123

10. China

11. State Key Laboratory of Chemo/Biosensing and Chemometrics

12. College of Chemistry and Chemical Engineering

13. Hunan University

14. Changsha 410082

15. Center of Materials Science and Engineering

16. Guangxi University of Science and Technology

17. Liuzhou 545006

Abstract

Two-electron oxidation of five aniline-based compounds 4,4′′-p/m-terphenyldiamines afforded the first isolable aniline-based diradical dications 12+52+.

Funder

National Key Research and Development Program of China

National Natural Science Foundation of China

Soochow University

Science and Technology Department of Guangxi Zhuang Autonomous

Guangxi University of Science and Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

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