Combining experiment and theory to elucidate the role of supercritical water in sulfide decomposition-Reference-Cited by-同舟云学术

Combining experiment and theory to elucidate the role of supercritical water in sulfide decomposition

Published:2014 Issue:20 Volume:16 Page:9220-9228
ISSN:1463-9076
Container-title:Phys. Chem. Chem. Phys.
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Kida Yuko¹²³,Class Caleb A.¹²³,Concepcion Anthony J.¹²³,Timko Michael T.⁴²⁵,Green William H.¹²³

Affiliation:

1. Massachusetts Institute of Technology

2. Department of Chemical Engineering

3. Cambridge, USA

4. Worcester Polytechnic Institute

5. Worcester, USA

Abstract

Supercritical water is observed to react with alkyl sulfides, forming H₂S, CO, and alkanes. Quantum chemistry calculations show this occurs via a multistep mechanism involving both free radical and pericyclic reactions, with water acting as both a reagent and a catalyst.

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2014/CP/C4CP00711E

Reference49 articles.

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