Autoinductive conversion of α,α-diiodonitroalkanes to amides and esters catalysed by iodine byproducts under O2-Reference-Cited by-同舟云学术

Autoinductive conversion of α,α-diiodonitroalkanes to amides and esters catalysed by iodine byproducts under O2

Published:2018 Issue:49 Volume:54 Page:6360-6363
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Li Jing¹²³⁴⁵,Lear Martin J.⁶⁷⁸⁹¹⁰^ORCID,Hayashi Yujiro¹²³⁴⁵^ORCID

Affiliation:

1. Department of Chemistry

2. Graduate School of Science

3. Tohoku University

4. Sendai 980-8578

5. Japan

6. School of Chemistry

7. University of Lincoln

8. Brayford Pool

9. Lincoln LN6 7TS

10. UK

Abstract

Studies to convert nitroalkanes into amides and esters using I₂ and O₂ revealed in situ-generated iodine species facilitate the homolytic C–I bond cleavage of α,α-diiodonitroalkanes, arguably in an autoinductive or autocatalytic manner.

Funder

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2018/CC/C8CC03191F

Reference32 articles.

1. Reaction Progress Kinetic Analysis: A Powerful Methodology for Mechanistic Studies of Complex Catalytic Reactions

2. Kinetic Profiling of Catalytic Organic Reactions as a Mechanistic Tool

3. Computational Organic Chemistry: Bridging Theory and Experiment in Establishing the Mechanisms of Chemical Reactions

4. Oxidative Amidation of Nitroalkanes with Amine Nucleophiles using Molecular Oxygen and Iodine

5. Mechanism of Oxidative Amidation of Nitroalkanes with Oxygen and Amine Nucleophiles by Using Electrophilic Iodine

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