Flow synthesis of hypercrosslinked polymers with additional microporosity that enhances CO<sub>2</sub>/N<sub>2</sub>separation-Reference-Cited by-同舟云学术

Flow synthesis of hypercrosslinked polymers with additional microporosity that enhances CO₂/N₂separation

Published:2023 Issue:18 Volume:11 Page:9859-9867
ISSN:2050-7488
Container-title:Journal of Materials Chemistry A
language:en
Short-container-title:J. Mater. Chem. A

Author:

Chanchaona Nadhita¹^ORCID,Ding Liang¹,Lin Shiliang¹^ORCID,Sarwar Sulaiman¹,Dimartino Simone¹^ORCID,Fletcher Ashleigh J.²^ORCID,Dawson Daniel M.³^ORCID,Konstas Kristina⁴,Hill Matthew R.⁴^ORCID,Lau Cher Hon¹^ORCID

Affiliation:

1. School of Engineering, University of Edinburgh, Robert Stevenson Road, EH9 3FK, UK

2. Department of Chemical and Process Engineering, University of Strathclyde, 75 Montrose Street, Glasgow, G1 1XJ, UK

3. School of Chemistry, EaStCHEM, Centre of Magnetic Resonance, University of St. Andrews, KY16 9ST, UK

4. CSIRO Manufacturing Flagship, Private Bag 10, Clayton South, Melbourne, Victoria 3169, Australia

Abstract

Continuous flow synthesis of hypercrosslinked polymers (HCPs) was achieved within 5 minutes, 99% faster than a batch reaction, improving productivity rates by 32-fold. The faster kinetics also enhanced microporosity, increasing CO2/N2selectivity by 850%.

Funder

National Metal and Materials Technology Center

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/TA/D2TA09253K

Reference53 articles.

1. Stepwise Crosslinking: A Facile Yet Versatile Conceptual Strategy to Nanomorphology-Persistent Porous Organic Polymers

2. Hypercrosslinked Aromatic Heterocyclic Microporous Polymers: A New Class of Highly Selective CO2Capturing Materials

3. Hypercrosslinked Polymers: A Review