Effect of transition metal cations on the local structure and lithium transport in disordered rock-salt oxides-Reference-Cited by-同舟云学术

Effect of transition metal cations on the local structure and lithium transport in disordered rock-salt oxides

Published:2022 Issue:10 Volume:24 Page:5823-5832
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Semykina D. O.¹^ORCID,Morkhova Ye. A.¹²³^ORCID,Kabanov A. A.¹²^ORCID,Mishchenko K. V.¹^ORCID,Slobodyuk A. B.¹⁴^ORCID,Kirsanova M. A.⁵^ORCID,Podgornova O. A.¹^ORCID,Shindrov A. A.¹^ORCID,Okhotnikov K. S.⁶^ORCID,Kosova N. V.¹^ORCID

Affiliation:

1. Institute of Solid State Chemistry and Mechanochemistry SB RAS, 18 Kutateladze, 630128 Novosibirsk, Russia

2. Samara State Technical University, Molodogvardeyskaya St. 244, 443100 Samara, Russia

3. Samara University, Academician Pavlov Str. 1, 443011, Samara, Russia

4. Institute of Chemistry, Far-Eastern Branch of the Russian Academy of Sciences, 159 pr. Stoletiya Vladivostoka, 690022 Vladisvostok, Russia

5. Skolkovo Institute of Science and Technology, 3 Nobel str., 121205 Moscow, Russia

6. Independent researcher, 31-421 Reduta 38/9, Kraków, Poland

Abstract

Lithium-excess oxides Li1.2Ti0.4Mn0.4O2 and Li1.3Nb0.3Mn0.4O2 with a disordered rock-salt structure and Mn3+/Mn4+ as a redox couple were compared to analyze the effect of different d0 metal ions on the local structure and Li+ ion migration.

Funder

Russian Foundation for Basic Research

Russian Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CP/D1CP04993C

Reference39 articles.

1. Unlocking the Potential of Cation-Disordered Oxides for Rechargeable Lithium Batteries

2. The structural and chemical origin of the oxygen redox activity in layered and cation-disordered Li-excess cathode materials