Structural and magnetic properties of semiquinonate based Al(iii) and Ga(iii) complexes-Reference-Cited by-同舟云学术

Structural and magnetic properties of semiquinonate based Al(iii) and Ga(iii) complexes

Published:2017 Issue:5 Volume:46 Page:1439-1448
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Das Chinmoy¹²³⁴,Shukla Pragya¹²³⁴,Sorace Lorenzo⁵⁶⁷⁸^ORCID,Shanmugam Maheswaran¹²³⁴

Affiliation:

1. Department of Chemistry

2. Indian Institute of Technology Bombay

3. Mumbai

4. India

5. Dipartimento di Chimica “U. Schiff” and UdR INSTM

6. Università degli Studi di Firenze

7. 50019 Sesto Fiorentino

8. Italy

Abstract

One electron reduced 3,5-di-t-butyl-o-benzoquinone reacts with anhydrous MCl₃ (M = Al or Ga) led us to isolate a Al(iii) dimer and a Ga(iii) monomer which are structurally characterized with the molecular formula of [Al₂(μ-HL⁻)₂(L˙⁻)₄] (1) and [Ga(L˙⁻)₃] (2). Detailed magnetic studies reveal that the radicals are coupled ferromagnetically. The EPR studies performed on 1 unequivocally discloses that the dimeric 1 is exists in equilibrium with monomeric [Al(L˙⁻)₃].

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/DT/C6DT04281C

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