Intramolecular N-coordination in ketiminoboranes-Reference-Cited by-同舟云学术

Intramolecular N-coordination in ketiminoboranes

Published:2015 Issue:12 Volume:44 Page:5284-5287
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Bacon Catherine E.¹²³⁴,Mansour Liz⁵⁶⁷⁸,Hayward John J.⁵⁶⁷⁸,Rawson Jeremy M.⁵⁶⁷⁸

Affiliation:

1. Department of Chemistry

2. The University of Cambridge

3. Cambridge CB2 1EW

4. UK

5. Department of Chemistry & Biochemistry

6. The University of Windsor

7. Windsor

8. Canada N9B 3P4

Abstract

Ketiminoboranes, R₂CNB-R′₂, pioneered by Wade et al., are formally isoelectronic with allenes but undergo intramolecular cyclisation when R = 2-pyridyl to form heterocyclic boranes with N-donor capability.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/DT/C5DT00196J

Reference27 articles.

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4. Non-innocent pyridyl nitrogens: unprecedented interconversion of N-bridgehead-thiadiazolium salts and thiatriazine in the generation of thiatriazinyl

5. Co-ordinative interactions in chelated complexes of silicon. Part 5. Chirality of five-co-ordinate silicon compounds: crystal and molecular structures of 1-(chlorodimethylsilyl)- and 1-(dichloromethylsilyl)-1,2,3,4-tetrahydro-1,10-phenanthroline

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