Photochemical charge accumulation in a heteroleptic copper(<scp>i</scp>)-anthraquinone molecular dyad <i>via</i> proton-coupled electron transfer-Reference-Cited by-同舟云学术

Photochemical charge accumulation in a heteroleptic copper(i)-anthraquinone molecular dyad via proton-coupled electron transfer

Published:2023 Issue:37 Volume:14 Page:10219-10235
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Xie Zhu-Lin¹^ORCID,Gupta Nikita¹²^ORCID,Niklas Jens¹^ORCID,Poluektov Oleg G.¹^ORCID,Lynch Vincent M.³,Glusac Ksenija D.¹²^ORCID,Mulfort Karen L.¹^ORCID

Affiliation:

1. Division of Chemical Sciences and Engineering, Argonne National Laboratory, USA

2. Department of Chemistry, University of Illinois at Chicago, USA

3. Department of Chemistry, University of Texas at Austin, USA

Abstract

An earth-abundant Cu(i) chromophore-anthraquinone dyad is reported to photochemically accumulate two electrons at the anthraquinone via proton-coupled electron transfer, generating the monoprotonated photoproduct.

Funder

Basic Energy Sciences

Argonne National Laboratory

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/SC/D3SC03428C

Reference95 articles.

1. Theoretical Insights into Heterogeneous (Photo)electrochemical CO2 Reduction

2. Design of molecular water oxidation catalysts with earth-abundant metal ions