Manganese-catalyzed oxidation of furfuryl alcohols and furfurals to efficient synthesis of furoic acids

Author:

Kou Tianshu1,Chen Weihua1,He Aimin1,Wang Xiaoru1,Li Xin1,Cui Bing2ORCID,Wu Zhiyong2,Zhao Mingqin2ORCID,Xie Min1,Shao Zhihui2ORCID

Affiliation:

1. Technology Center of China Tobacco Hebei Industrial Co., Ltd, Shijiazhuang 050051, China

2. Flavors and Fragrance Engineering & Technology Research Center of Henan Province, College of Tobacco Science Henan Agricultural University, Zhengzhou 450002, China

Abstract

Herein, the direct oxidation of furfuryl alcohols and furfurals to the corresponding furoic acids is performed highly efficiently with potassium hydroxide as the base in the presence of a catalytic amount of PNP pincer manganese catalyst in dioxane.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

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