Arene-ligated heteroleptic terphenolate complexes of thorium-Reference-Cited by-同舟云学术

Arene-ligated heteroleptic terphenolate complexes of thorium

Published:2014 Issue:46 Volume:43 Page:17416-17421
ISSN:1477-9226
Container-title:Dalton Trans.
language:en
Short-container-title:Dalton Trans.

Author:

McKinven Jamie¹²³⁴,Nichol Gary S.¹²³⁴,Arnold Polly L.¹²³⁴

Affiliation:

1. EaStCHEM School of Chemistry

2. Joseph Black Building

3. University of Edinburgh

4. Edinburgh, UK

Abstract

Bulky terphenolate ligands allow the synthesis of rare heteroleptic thorium chloride, and borohydride complexes; in the absence of donor solvents, the terphenolate ligands protect the metal ions through neutral Th–η⁶-arene interactions in a thorium bis(arene) sandwich motif.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2014/DT/C4DT02995J

Reference33 articles.

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