Efficient O- and S-glycosylation with ortho-2,2-dimethoxycarbonylcyclopropylbenzyl thioglycoside donors by catalytic strain-release-Reference-Cited by-同舟云学术

Efficient O- and S-glycosylation with ortho-2,2-dimethoxycarbonylcyclopropylbenzyl thioglycoside donors by catalytic strain-release

Published:2024 Issue:10 Volume:15 Page:3711-3720
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Ding Han¹^ORCID,Lv Jian¹,Zhang Xiao-Lin¹^ORCID,Xu Yuan¹^ORCID,Zhang Yu-Han¹,Liu Xue-Wei¹²^ORCID

Affiliation:

1. School of Chemistry, Chemical Engineering and Biotechnology, Nanyang Technological University, 21 Nanyang Link, 637371, Singapore

2. Key Laboratory of Marine Drugs of Ministry of Education, Shandong Key Laboratory of Glycoscience and Glycotechnology, School of Medicine and Pharmacy, Ocean University of China, Qingdao, Shandong, 266003, China

Abstract

An efficient glycosylation reaction utilizing a meticulously designed thioglycoside has been developed. The well-established protocol was demonstrated in the total synthesis of TD139 and a one-pot assembly of E. coli O33 antigen tetrasaccharide.

Funder

Agency for Science, Technology and Research

Ministry of Education - Singapore

National Research Foundation Singapore

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/SC/D3SC06619C

Reference55 articles.

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