Dramatic slowing down of the conformational equilibrium in the silyl derivative of glucose in the vicinity of the glass transition temperature-Reference-Cited by-同舟云学术

Dramatic slowing down of the conformational equilibrium in the silyl derivative of glucose in the vicinity of the glass transition temperature

Published:2019 Issue:37 Volume:15 Page:7429-7437
ISSN:1744-683X
Container-title:Soft Matter
language:en
Short-container-title:Soft Matter

Author:

Wolnica K.¹²³⁴⁵^ORCID,Dulski M.⁵³⁴⁶²^ORCID,Kamińska E.⁷⁸⁹¹⁰⁴^ORCID,Tarnacka M.¹²³⁴⁵^ORCID,Wrzalik R.¹²³⁴⁵,Zięba A.¹¹⁸⁹¹⁰⁴,Kasprzycka A.¹²¹³¹⁴⁴¹⁵,Nowak M.¹⁵¹⁶¹⁴⁴,Jurkiewicz K.¹²³⁴⁵^ORCID,Szeja W.¹²¹³¹⁴⁴¹⁵,Kamiński K.¹²³⁴⁵^ORCID,Paluch M.¹²³⁴⁵

Affiliation:

1. Institute of Physics

2. University of Silesia

3. 41-500 Chorzow

4. Poland

5. Silesian Center for Education and Interdisciplinary Research

6. Institute of Material Science

7. Department of Pharmacognosy and Phytochemistry

8. Medical University of Silesia in Katowice

9. School of Pharmacy with the Division of Laboratory Medicine in Sosnowiec

10. 41-200 Sosnowiec

11. Department of Organic Chemistry

12. Silesian Technical University of Technology

13. Department of Chemistry

14. 44-100 Gliwice

15. Biotechnology Centre

16. Silesian University of Technology

Abstract

This paper reports significantly slowed down of the rotations of silyl moieties along with the deformation in the saccharide ring in 1,2,3,4,6-penta-O-(trimethylsilyl)-d-glucopyranose (S-GLU) in the vicinity of the glass transition temperature.

Funder

Narodowe Centrum Nauki

Publisher

Royal Society of Chemistry (RSC)

Subject

Condensed Matter Physics,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/SM/C9SM01259A

Reference38 articles.

1. The lifetime of the deviations from bulk behaviour in polymers confined at the nanoscale

2. How irreversible adsorption affects interfacial properties of polymers

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4. Adsorption Kinetics of Ultrathin Polymer Films in the Melt Probed by Dielectric Spectroscopy and Second-Harmonic Generation

5. Interplay between Core and Interfacial Mobility and Its Impact on the Measured Glass Transition: Dielectric and Calorimetric Studies

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