Mechanism of supported Ru3Sn7 nanocluster-catalyzed selective hydrogenation of coconut oil to fatty alcohols-Reference-Cited by-同舟云学术

Mechanism of supported Ru3Sn7 nanocluster-catalyzed selective hydrogenation of coconut oil to fatty alcohols

Published:2018 Issue:5 Volume:8 Page:1322-1332
ISSN:2044-4753
Container-title:Catalysis Science & Technology
language:en
Short-container-title:Catal. Sci. Technol.

Author:

Luo Zhicheng¹²³⁴⁵,Bing Qiming⁶⁷⁸⁹⁵,Kong Jiechen¹²³⁴⁵,Liu Jing-yao⁶⁷⁸⁹⁵^ORCID,Zhao Chen¹²³⁴⁵^ORCID

Affiliation:

1. Shanghai Key Laboratory of Green Chemistry and Chemical Processes

2. School of Chemistry and Molecular Engineering

3. East China Normal University

4. Shanghai

5. China

6. Laboratory of Theoretical and Computational Chemistry

7. Institute of Theoretical Chemistry

8. Jilin University

9. Changchun

Abstract

As a promising hydrotreating catalyst, it was previously reported that Ru⋯OSn (Ru electronically interacts with Sn oxides) on RuSn/SiO₂ was the active site for fatty acid hydrogenation, but here in this work we found that Ru₃Sn₇ nanoclusters on RuSn/SiO₂ were responsible for the selective hydrogenation of diverse fatty acids and coconut oil to fatty alcohols.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2018/CY/C8CY00037A

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