Conformational equilibria in acrolein–CO<sub>2</sub>: the crucial contribution of n → π* interactions unveiled by rotational spectroscopy-Reference-Cited by-同舟云学术

Conformational equilibria in acrolein–CO₂: the crucial contribution of n → π* interactions unveiled by rotational spectroscopy

Published:2024 Issue:27 Volume:26 Page:18865-18870
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Wang Hao¹²,Chen Junhua³^ORCID,Tian Xiao¹,Wang Chenxu¹,Lan Junlin¹,Liu Xingchen²^ORCID,Zhang Zhenhua²,Wen Xiaodong²^ORCID,Gou Qian¹^ORCID

Affiliation:

1. School of Chemistry and Chemical Engineering, Chongqing University, Daxuecheng South Rd 55, 401331, Chongqing, China

2. State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taoyuan South Rd. 27, Taiyuan 030001, Shanxi, China

3. School of Pharmacy, Guizhou Medical University, Guiyang 550025, Guizhou, China

Abstract

Using Fourier-transform microwave spectroscopy complemented by theoretical analysis, this study delivers a comprehensive depiction of the physical origin of the ‘n → π* interaction’ between CO2 and acrolein.

Funder

State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences

National Natural Science Foundation of China

National Key Research and Development Program of China

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/CP/D4CP01650E

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