Structural diversity of alkylzinc complexes with pyrrole-based N,O-ligands: from molecular complexes to coordination polymers
Author:
Affiliation:
1. Institute of Physical Chemistry
2. Polish Academy of Sciences
3. 01-224 Warsaw
4. Poland
5. Department of Chemistry
6. Warsaw University of Technology
7. 00-664 Warsaw
Abstract
The equimolar reaction of R2Zn (where R = Et or tBu) with pyrrole-based N,O-proligands afforded a series of alkylzinc compounds with a variety of structures including a macrocyclic complex and 1D coordination polymers with versatile intramolecular or intermolecular bonding modes.
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2016/DT/C6DT00674D
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5. Divergent coordination mode of magnesium and zinc alkyls supported by the bifunctional pyrrolylaldiminato ligand
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