Kinetic and thermodynamic sorption studies of Fe(iii) and Zr(iv) by DFO@Purolite, a desferrioxamine B based chelating resin

Author:

Alberti Giancarla1ORCID,Zanoni Camilla1,Losi Vittorio1,Rovertoni Sara1,Magnaghi Lisa Rita1ORCID,Fonquernie Osian2,Brandès Stéphane2,Amati Agnese3,Chambron Jean-Claude3ORCID,Maudoux Nicolas4,Biesuz Raffaela1ORCID,Meyer Michel2ORCID

Affiliation:

1. Dipartimento di Chimica – Università degli Studi di Pavia, via Taramelli 12, 27100 Pavia, Italy

2. Institut de Chimie Moléculaire de l’Université de Bourgogne (ICMUB), UMR 6302, CNRS, Université de Bourgogne, 9 avenue Alain Savary, BP 47870, 21078 Dijon Cedex, France

3. Institut de Chimie de Strasbourg, UMR 7177, CNRS, Université de Strasbourg, 1 rue Blaise Pascal, BP 296 R 8, 67008 Strasbourg Cedex, France

4. TrisKem International, 3 rue des Champs Géons, ZAC de l’Éperon, 35170 Bruz, France

Abstract

DFO@Purolite resin efficiently sorbs Fe(iii) and Zr(iv) above pH 1. The Gibbs–Donnan model enabled to determine the stoichiometry and stability of the complexes formed in the solid phase and to predict the sorption behaviour of the material.

Funder

Agence Nationale de la Recherche

Centre National de la Recherche Scientifique

Conseil régional de Bourgogne-Franche-Comté

Federal Energy Management Program

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Reference56 articles.

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4. The chemistry of PET imaging with zirconium-89

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