Anisotropic charge-transfer effects in the asymmetric Fe(CN)5NO octahedron of sodium nitroprusside: a soft X-ray absorption spectroscopy study-Reference-Cited by-同舟云学术

Anisotropic charge-transfer effects in the asymmetric Fe(CN)5NO octahedron of sodium nitroprusside: a soft X-ray absorption spectroscopy study

Published:2014 Issue:15 Volume:16 Page:7031-7036
ISSN:1463-9076
Container-title:Phys. Chem. Chem. Phys.
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Nanba Yu̅suke¹²³,Asakura Daisuke¹²³,Okubo Masashi¹²³,Zhou Haoshen¹²³,Amemiya Kenta⁴⁵⁶³,Okada Kozo⁷⁸⁹,Glans Per-Anders¹⁰¹¹¹²,. Jenkins Catherine A¹⁰¹¹¹²,Arenholz Elke¹⁰¹¹¹²,Guo Jinghua¹⁰¹¹¹²

Affiliation:

1. Energy Technology Research Institute

2. National Institute of Advanced Industrial Science and Technology

3. Tsukuba, Japan

4. Photon Factory

5. IMSS

6. High Energy Accelerator Research Organization

7. The Graduate School of Natural Science and Technology

8. Okayama University

9. Okayama 700-8530, Japan

10. Advanced Light Source

11. Lawrence Berkeley National Laboratory

12. Berkeley, USA

Abstract

The electronic structure of Na₂[Fe(CN)₅NO]·2H₂O (sodium nitroprusside: SNP) was investigated by using soft X-ray absorption (XA) spectroscopy and a configuration-interaction full-multiplet calculation for the [Fe(CN)₅NO]²⁻cluster model.

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2014/CP/C3CP55471F

Reference36 articles.

1. Anisotropic holographic scattering in centrosymmetric sodium nitroprusside

2. Holographic recording with orthogonally polarized waves in centrosymmetric Na 2 [Fe(CN) 5 NO]·2H 2 O

3. Photoinduced Linkage Isomers of Transition-Metal Nitrosyl Compounds and Related Complexes

4. Three Redox States of Nitrosyl: NO+, NO., and NO−/HNO Interconvert Reversibly on the Same Pentacyanoferrate(II) Platform

5. Electronic structure and local geometry of Na2[Fe(CN)5NO]·2H2O single crystals investigated by polarization-dependent X-ray absorption spectroscopy

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