Total synthesis of four stereoisomers of methyl 4,8,12-trimethylpentadecanoate, a major component of the sex pheromone of the stink bug Edessa meditabunda-Reference-Cited by-同舟云学术

Total synthesis of four stereoisomers of methyl 4,8,12-trimethylpentadecanoate, a major component of the sex pheromone of the stink bug Edessa meditabunda

Published:2020 Issue:26 Volume:18 Page:5034-5044
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Szczerbowski Daiane¹²³⁴⁵^ORCID,Schulz Stefan⁶⁷⁸⁹^ORCID,Zarbin Paulo Henrique Gorgatti¹²³⁴⁵^ORCID

Affiliation:

1. Laboratório de Semioquímicos

2. Chemistry Department

3. Federal University of Paraná

4. 81531-990 Curitiba

5. Brazil

6. Institute of Organic Chemistry

7. Technische Universität Braunschweig

8. 38106 Braunschweig

9. Germany

Abstract

A convergent synthetic route was developed for the stereoselective synthesis of four stereoisomers of methyl 4,8,12-trimethylpentadecanoate. The Fouquet-Schlosser variant of the Grignard reaction was used as key steps.

Funder

Instituto Nacional de Ciência e Tecnologia de Semioquímicos na Agricultura

Conselho Nacional de Desenvolvimento Científico e Tecnológico

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/OB/D0OB00862A

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