Characterization in aqueous medium of an FMN semiquinone radical stabilized by the enzyme-like microenvironment of a modified polyethyleneimine-Reference-Cited by-同舟云学术

Characterization in aqueous medium of an FMN semiquinone radical stabilized by the enzyme-like microenvironment of a modified polyethyleneimine

Published:2020 Issue:23 Volume:18 Page:4386-4389
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Chevalier Yoan¹²³⁴⁵,Lock Toy Ki Yvette⁶⁷⁸⁹¹⁰,Herrero Christian¹²³⁴⁵^ORCID,le Nouën Didier⁶⁷⁸⁹¹⁰,Mahy Jean-Pierre¹²³⁴⁵^ORCID,Goddard Jean-Philippe⁶⁷⁸⁹¹⁰^ORCID,Avenier Frédéric¹²³⁴⁵^ORCID

Affiliation:

1. ICMMO

2. UMR CNRS 8182

3. Université Paris Saclay

4. rue du doyen Georges Poitou

5. 91405 Orsay

6. LIMA

7. UMR CNRS 7042

8. Université de Haute-Alsace

9. Université de Strasbourg

10. 68100 Mulhouse

Abstract

The elusive flavin semiquinone intermediate found in flavoproteins such as cryptochromes has been obtained in aqueous solution by single electron reduction of the natural FMN cofactor using sodium ascorbate.

Funder

Agence Nationale de la Recherche

Institut Universitaire de France

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/OB/D0OB00864H

Reference30 articles.

1. Flavogenomics - a genomic and structural view of flavin-dependent proteins

2. The Chemical and Biological Versatility of Riboflavin

3. Baeyer−Villiger Monooxygenases: More Than Just Green Chemistry

4. Recent Developments in the Application of Baeyer-Villiger Monooxygenases as Biocatalysts

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