Affiliation:
1. School of Chemistry, University of Glasgow, Glasgow, G12 8QQ, UK
Abstract
Sulfonyl azides undergo rapid inverse electron demand SPAAC with strained alkynes to deliver 1-sulfonyl-1,2,3-triazoles. Treatment of these with Rh(ii) carboxylate catalyst promotes denitrogenation and transannular 1,5-H insertion or 1,2-H shift.
Publisher
Royal Society of Chemistry (RSC)
Subject
Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis
Cited by
2 articles.
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