C–H functionalization of quinoline N-oxides catalyzed by Pd(<scp>ii</scp>) complexes: a computational study-Reference-Cited by-同舟云学术

C–H functionalization of quinoline N-oxides catalyzed by Pd(ii) complexes: a computational study

Published:2023 Issue:34 Volume:25 Page:22755-22767
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Costa Paulo J.¹^ORCID,Martins Frederico F.¹^ORCID,Pi Chao²^ORCID,Cui Xiuling²^ORCID,Calhorda Maria José¹^ORCID

Affiliation:

1. BioISI – Instituto de Biossistemas e Ciências Integrativas, Departamento de Química e Bioquímica, Faculdade de Ciências, Universidade de Lisboa, Campo Grande, 1749-016 Lisboa, Portugal

2. College of Chemistry, Henan Key Laboratory of Chemical Biology and Organic Chemistry, Key Laboratory of Applied Chemistry of Henan Universities, Zhengzhou University, Zhengzhou 450052, People's Republic of China

Abstract

Pd(ii)Cl2catalysts favor the regioselective C8–H activation of quinoline N-oxides owing to the higher stability of the σ-complex, in contrast to Pd(ii) acetate which favors C2–H activation.

Funder

Fundação para a Ciência e a Tecnologia

Ministry of Science and Technology of the People's Republic of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2023/CP/D3CP02445H

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