Quantum dynamics of polyatomic dissociative chemisorption on transition metal surfaces: mode specificity and bond selectivity

Author:

Jiang Bin12345ORCID,Yang Minghui678910,Xie Daiqian1112131415,Guo Hua1234

Affiliation:

1. Department of Chemistry and Chemical Biology

2. University of New Mexico

3. Albuquerque

4. USA

5. Department of Chemical Physics

6. Key Laboratory of Magnetic Resonance in Biological Systems

7. State Key Laboratory of Magnetic Resonance and Atomic and Molecular Physics

8. Wuhan Centre for Magnetic Resonance

9. Wuhan Institute of Physics and Mathematics

10. Chinese Academy of Sciences

11. Institute of Theoretical and Computational Chemistry

12. Key Laboratory of Mesoscopic Chemistry

13. School of Chemistry and Chemical Engineering

14. Nanjing University

15. Nanjing 210093

Abstract

Recent advances in quantum dynamical characterization of polyatomic dissociative chemisorption on accurate global potential energy surfaces are critically reviewed.

Funder

Division of Chemistry

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Reference206 articles.

1. G. A. Somorjai , Introduction to Surface Chemistry and Catalysis, Wiley, New York, 1994

2. A. Nilsson , L. G. M.Petersson and J. K.Nørskov, Chemical Bonding at Surface and Interfaces, Elsevier, Amsterdam, 2008

3. I. Chorkendorff and J. W.Niemantsverdriet, Concepts of Modern Catalysis and Kinetics, Wiley-VCH, Weinheim, 2003

4. Primary steps in catalytic synthesis of ammonia

5. A kinetic model of the water gas shift reaction

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