Caught! Crystal trapping of a side-on peroxo bound to Cr(iv)-Reference-Cited by-同舟云学术

Caught! Crystal trapping of a side-on peroxo bound to Cr(iv)

Published:2015 Issue:14 Volume:51 Page:2802-2805
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

de Sousa David P.¹²³⁴⁵^ORCID,Bigelow Jennifer O.⁶⁷⁸⁹,Sundberg Jonas¹²³⁴⁵,Que Lawrence⁶⁷⁸⁹,McKenzie Christine J.¹²³⁴⁵

Affiliation:

1. Department of Physics

2. Chemistry and Pharmacy

3. University of Southern Denmark

4. 5230 Odense M

5. Denmark

6. Department of Chemistry and Center for Metals in Biocatalysis

7. University of Minnesota

8. Minneapolis

9. USA

Abstract

A Cr(iv)η²–peroxo complex is a likely intermediate in catalytic disproportionation of H₂O₂ in solution – and solid state.

Funder

Danish National Research Foundation

Division of Chemistry

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2015/CC/C4CC08785B

Reference25 articles.

1. Oxygen activating nonheme iron enzymes

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4. Molecular Catalysts for Water Oxidation

5. A structure-based catalytic mechanism for the xanthine oxidase family of molybdenum enzymes.

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