Robust and electron deficient oxidovanadium(iv) porphyrin catalysts for selective epoxidation and oxidative bromination reactions in aqueous media-Reference-Cited by-同舟云学术

Robust and electron deficient oxidovanadium(iv) porphyrin catalysts for selective epoxidation and oxidative bromination reactions in aqueous media

Published:2019 Issue:7 Volume:21 Page:1757-1768
ISSN:1463-9262
Container-title:Green Chemistry
language:en
Short-container-title:Green Chem.

Author:

Dar Tawseef Ahmad¹²³⁴,Uprety Bhawna¹²³⁴^ORCID,Sankar Muniappan¹²³⁴^ORCID,Maurya Mannar R.¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. Indian Institute of Technology Roorkee

3. Roorkee – 247667

4. India

Abstract

Octamethoxy vanadylporphyrin (1) and its perbromo derivative (2) have been synthesized. 2 exhibited 100% selectivity for epoxide formation with very high TOF numbers. Remarkably, 2 biomimics vanadium bromoperoxidase (VBrPO) enzyme with extremely high TOF value in water.

Funder

Ministry of Human Resource Development

Science and Engineering Research Board

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Environmental Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/GC/C8GC03909G

Reference72 articles.

1. Transition-metal-catalyzed epoxidations

2. K. Bauer , D.Garbe and H.Surburg , Common Fragrance and Flavor Materials , Wiley-VCH Verlag GmbH , Weinheim, FRG , 2001

3. Recent developments on the epoxidation of alkenes using hydrogen peroxide as an oxidant

4. G. Sainel , R.Reith and K. T.Rowbottom , Ullmann's Encyclopedia of Industrial Chemistry , Wiley-VCH Verlag GmbH & Co. KGaA , Weinheim, Germany , 2000

5. R. A. Sheldon and J. K.Kochi , Metal-catalyzed oxidations of organic compounds: mechanistic principles and synthetic methodology including biochemical processes , Academic Press , 1981

Cited by 46 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Photoelectrocatalytic application of vanadylporphyrin complexes directly extracted from oil;Catalysis Today;2024-11

2. Synthesis and characterization of meso-substituted oxidovanadium (IV) porphyrins for the selective epoxidation of alkenes in the presence of bicarbonate-assisted H2O2;Polyhedron;2024-10

3. An insight into the concept of neuroinflammation and neurodegeneration in Alzheimer’s disease: targeting molecular approach Nrf2, NF-κB, and CREB;Inflammopharmacology;2024-06-29

4. Synthesis of Vanadyl Complexes of N-Confused Porphyrins and Their Bromoperoxidase-like Catalytic Activity;Inorganic Chemistry;2024-06-24

5. Enhanced Catalytic Activity of Binuclear Oxidovanadium(IV) Bisbenzimidazole Linked Porphyrin Dimer for the Generation of Biologically Active 3,4-Dihydropyrimidinones and Their Corresponding Thiones;Inorganic Chemistry;2024-06-04