The enantioselectivity in asymmetric ketone hydrogenation catalyzed by RuH2(diphosphine)(diamine) complexes: insights from a 3D-QSSR and DFT study-Reference-Cited by-同舟云学术

The enantioselectivity in asymmetric ketone hydrogenation catalyzed by RuH2(diphosphine)(diamine) complexes: insights from a 3D-QSSR and DFT study

Published:2016 Issue:12 Volume:6 Page:4450-4457
ISSN:2044-4753
Container-title:Catalysis Science & Technology
language:en
Short-container-title:Catal. Sci. Technol.

Author:

Li Longfei¹²³⁴⁵,Pan Yuhui¹²³⁴⁵,Lei Ming¹²³⁴⁵

Affiliation:

1. State Key Laboratory of Chemical Resource Engineering

2. Institute of Materia Medica

3. College of Science

4. Beijing University of Chemical Technology

5. Beijing

Abstract

The 3D-QSSR method was carried out to investigate the enantioselectivity of the asymmetric ketone hydrogenation (AKH) catalyzed by RuH₂(diphosphine)(diamine) complexes integrating with DFT method, which could provide a way to design homogeneous transition-metal catalysts.

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2016/CY/C5CY01225B

Reference77 articles.

1. Pioneering Perspectives on Asymmetric Hydrogenation†

2. Enantioselective catalysis in fine chemicals production

3. Industrial-Scale Synthesis and Applications of Asymmetric Hydrogenation Catalysts

4. Exploiting Metal–Ligand Bifunctional Reactions in the Design of Iron Asymmetric Hydrogenation Catalysts

5. BINAP: an efficient chiral element for asymmetric catalysis

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