A stereospecific total synthesis of <scp>dl</scp>-hexahydroapoerysopine-Reference-Cited by-同舟云学术

A stereospecific total synthesis of dl-hexahydroapoerysopine

Published:2022 Issue:45 Volume:58 Page:6506-6509
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Fang Da-Shu¹,Deng Jun¹,Zheng Jianfeng²^ORCID,Li Wei-Dong Z.¹²^ORCID

Affiliation:

1. Chongqing Key Laboratory of Natural Product Synthesis and Drug Research, School of Pharmaceutical Sciences, Chongqing University, Chongqing 401331, China

2. Sichuan Engineering Research Center for Biomimetic Synthesis of Natural Drugs, School of Life Science and Engineering, Southwest Jiaotong University, Chengdu 610031, China

Abstract

An efficient acid-mediated stereospecific skeletal rearrangement for the total synthesis of dl-hexahydroapoerysopine, an intriguing and historically important Apo rearrangement product of the aromatic Erythrina alkaloids, is described.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CC/D2CC01892F

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