Efficient synthesis of 2-methylene-4-phenyl-1,3-dioxolane, a cyclic ketene acetal for controlling the NMP of methyl methacrylate and conferring tunable degradability-Reference-Cited by-同舟云学术

Efficient synthesis of 2-methylene-4-phenyl-1,3-dioxolane, a cyclic ketene acetal for controlling the NMP of methyl methacrylate and conferring tunable degradability

Published:2016 Issue:26 Volume:7 Page:4427-4435
ISSN:1759-9954
Container-title:Polymer Chemistry
language:en
Short-container-title:Polym. Chem.

Author:

Tran Johanna¹²³⁴⁵,Guégain Elise¹²³⁴⁵,Ibrahim Nada¹²³⁴⁵,Harrisson Simon⁶⁷⁸⁹¹⁰,Nicolas Julien¹²³⁴⁵^ORCID

Affiliation:

1. Institut Galien Paris-Sud

2. UMR CNRS 8612

3. Univ Paris-Sud

4. Faculté de Pharmacie

5. F-92296 Châtenay-Malabry cedex

6. Laboratoire des IMRCP

7. Université de Toulouse

8. CNRS UMR 5623

9. Université Paul Sabatier

10. France

Abstract

The efficient and reliable synthesis of 2-methylene-4-phenyl-1,3-dioxolane (MPDL) was reported and MPDL was used as a controlling comonomer for nitroxide-mediated polymerization of methyl methacrylate to give degradable copolymers.

Funder

Agence Nationale de la Recherche

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering

Link

http://pubs.rsc.org/en/content/articlepdf/2016/PY/C6PY00778C

Reference48 articles.

1. Degradable vinyl polymers for biomedical applications

2. Chemistry, chances and limitations of the radical ring-opening polymerization of cyclic ketene acetals for the synthesis of degradable polyesters

3. Free-Radical Ring-Opening Polymerization of Cyclic Allylic Sulfides