C–ON bond homolysis of alkoxyamines: when too high polarity is detrimental-Reference-Cited by-同舟云学术

C–ON bond homolysis of alkoxyamines: when too high polarity is detrimental

Published:2017 Issue:29 Volume:15 Page:6167-6176
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Nkolo Paulin¹²³⁴⁵,Audran Gérard¹²³⁴⁵,Bikanga Raphael⁶⁷⁸,Brémond Paul¹²³⁴⁵,Marque Sylvain R. A.¹²³⁴⁵^ORCID,Roubaud Valérie¹²³⁴⁵

Affiliation:

1. Aix Marseille Univ

2. CNRS

3. ICR

4. UMR 7273

5. 13397 Marseille Cedex 20

6. Laboratoire de Substances Naturelles et de Synthèse Organométalliques Université des Sciences et Techniques de Masuku

7. Franceville

8. Gabon

Abstract

In this article, previous multi-parameter linear relationships are amended using a parabolic model to describe the effect of EWGs in the alkyl fragment of alkoxyamines on the homolysis rate constant k_d.

Funder

Agence Nationale de la Recherche

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/OB/C7OB01312D

Reference43 articles.

1. Labile alkoxyamines: past, present, and future

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3. Alkoxyamine with reduced homolysis temperature and its application in repeated autonomous self-healing of stiff polymers

4. Dynamic Microcrystal Assembly by Nitroxide Exchange Reactions

5. Convergent synthesis of digitally-encoded poly(alkoxyamine amide)s

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