Chiral selectivity <i>vs.</i> noise in spontaneous mirror symmetry breaking-Reference-Cited by-同舟云学术

Chiral selectivity vs. noise in spontaneous mirror symmetry breaking

Published:2023 Issue:46 Volume:25 Page:31583-31595
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Hochberg David¹^ORCID,Buhse Thomas²^ORCID,Micheau Jean-Claude³^ORCID,Ribó Josep M.⁴^ORCID

Affiliation:

1. Department of Molecular Evolution, Centro de Astrobiología (CSIC-INTA), Carretera Ajalvir Kilómetro 4, 28850 Torrejón de Ardoz, Madrid, Spain

2. Centro de Investigaciones Químicas, IICBA, Universidad Autónoma del Estado de Morelos, 62209 Cuernavaca, Morelos, Mexico

3. Laboratoire Softmat (ex IMRCP), UMR au Centre National de la Recherche Scientifique No. 5623, Université Paul Sabatier, F-31062 Toulouse, France

4. Department of Organic and Inorganic Chemistry, Institute of Cosmos Science (IEEC-UB), University of Barcelona, Barcelona, Catalonia, Spain

Abstract

Imperfect bifurcation (blue curves) due to chiral bias g > 0 with chiral noise ξ induced by temperature fluctuations. Axis α = ([L] − [D])/2; λ is a nonequilibrium constraint on the system (a flow rate). Chiral selectivity holds when g > ξ.

Funder

Ministerio de Ciencia y Tecnología

Consejo Nacional de Ciencia y Tecnología

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2023/CP/D3CP03311B

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