Alkali metal complexes as efficient catalysts for hydroboration and cyanosilylation of carbonyl compounds
Author:
Affiliation:
1. Department of Chemistry
2. Indian Institute of Technology Hyderabad Kandi – 502 285
3. Sangareddy
4. India
5. Department of Applied Chemistry
6. Indian Institute of Technology (ISM) Dhanbad
Abstract
Catalytic hydroboration of aldehydes and ketones with pinacolborane (HBpin) and catalytic cyanosilylation of carbonyl compounds with trimethylsilyl cyanide using alkali metal (Li, Na, K) complexes as precatalysts under mild conditions are reported.
Funder
Japan International Cooperation Agency
Council of Scientific and Industrial Research
University Grants Commission
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2018/DT/C8DT02032A
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