Egg-shell structured LiCoO2 by Cu2+ substitution to Li+ sites via facile stirring in an aqueous copper(ii) nitrate solution

Author:

Kim Jaemin1234,Kang Hyunchul12345,Go Nakgyu1234,Jeong Seonghun1234,Yim Taeeun6234,Jo Yong Nam5789,Lee Kyu Tae101112413ORCID,Mun Junyoung1234ORCID

Affiliation:

1. Department of Energy and Chemical Engineering

2. Incheon National University

3. Incheon 22012

4. Republic of Korea

5. Advanced Batteries Research Center

6. Department of Chemistry

7. Korea Electronics Technology Institute

8. Seongnam

9. Korea

10. Department of Chemical and Biological Engineering

11. Seoul National University

12. Seoul 08826

13. Institute of Chemical Process

Abstract

For practical, high-energy lithium ion batteries, we introduce an egg-shell structured LiCoO2, enabling a credible performance with a high cut-off potential of 4.4 V, simply prepared by only stirring in 0.5 mM Cu(NO3)2 aqueous solution at room temperature without costly heat treatment.

Funder

National Research Foundation of Korea

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

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