Rh(iii)-Catalyzed sulfonylamination of α-indolyl alcohols via Csp2–Csp3 bond cleavage-Reference-Cited by-同舟云学术

Rh(iii)-Catalyzed sulfonylamination of α-indolyl alcohols via Csp2–Csp3 bond cleavage

Published:2021 Issue:5 Volume:8 Page:983-987
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Hu Xinwei¹²³⁴⁵,Tan Zheng¹²³⁴⁵,Liu Zhipeng¹²³⁴⁵,Chen Fengjuan¹²³⁴⁵,Jiang Huanfeng¹²³⁴⁵^ORCID,Zeng Wei¹²³⁴⁵^ORCID

Affiliation:

1. Key Laboratory of Functional Molecular Engineering of Guangdong Province

2. School of Chemistry and Chemical Engineering

3. South China University of Technology

4. Guangzhou 510641

5. China

Abstract

A Rh(iii)-catalyzed beta-carbon amination of α-aryl alcohols with sulfonyl azides has been developed. This transformation features unstrained Csp²–Csp³ σ bond amination via C–C bond cleavage, and provides a direct approach to complex 2-aminoindoles.

Funder

National Key Research and Development Program of China

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/QO/D0QO01426E

Reference39 articles.

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