Benzene-fused porphyrin(2.1.2.1) array: synthesis, structure, and electrocatalytic hydrogen evolution

Author:

Dong Yuting1,Qian Long1,Chen Feng1,Wang Yue1,Zhang Tao1ORCID,Qiu Fengxian1ORCID,Teranishi Toshiharu2ORCID,Xue Songlin1ORCID

Affiliation:

1. School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang, 212013, China

2. Graduate School of Science and Institute for Chemical Research, Kyoto University, Gokasho, Uji, Kyoto 611-0011, Japan

Abstract

Benzene-fused porphyrin(2.1.2.1) copper shows a S-shaped molecular conformation and multielectron donating and accepting properties. It displays a remarkably ability for electrocatalytic hydrogen evolution than the porphyrin(2.1.2.1) copper.

Funder

National Natural Science Foundation of China

Jiangsu University

Publisher

Royal Society of Chemistry (RSC)

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