Synthesis, structure and stereodynamics of atropisomeric N-chloroamides

Author:

Campbell Aaron D. G.1ORCID,Roper Natalie J.1,Waddell Paul G.1,Wills Corinne1ORCID,Dixon Casey M.1ORCID,Denton Ross M.2ORCID,Ermanis Kristaps2ORCID,Armstrong Roly J.1ORCID

Affiliation:

1. Chemistry – School of Natural and Environmental Sciences, Newcastle University, Newcastle Upon Tyne, NE1 7RU, UK

2. School of Chemistry, University Park, Nottingham, UK

Abstract

Novel atropisomeric N-chloroamides were prepared by efficient halogenation reactions and shown to racemize via a pathway involving geared bond rotation.

Funder

Engineering and Physical Sciences Research Council

Royal Society

Newcastle University

Publisher

Royal Society of Chemistry (RSC)

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