Synthesis, structure and stereodynamics of atropisomeric <i>N</i>-chloroamides-Reference-Cited by-同舟云学术

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Synthesis, structure and stereodynamics of atropisomeric N-chloroamides

Published:2024 Issue:28 Volume:60 Page:3818-3821
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Campbell Aaron D. G.¹^ORCID,Roper Natalie J.¹,Waddell Paul G.¹,Wills Corinne¹^ORCID,Dixon Casey M.¹^ORCID,Denton Ross M.²^ORCID,Ermanis Kristaps²^ORCID,Armstrong Roly J.¹^ORCID

Affiliation:

1. Chemistry – School of Natural and Environmental Sciences, Newcastle University, Newcastle Upon Tyne, NE1 7RU, UK

2. School of Chemistry, University Park, Nottingham, UK

Abstract

Novel atropisomeric N-chloroamides were prepared by efficient halogenation reactions and shown to racemize via a pathway involving geared bond rotation.

Funder

Engineering and Physical Sciences Research Council

Royal Society

Newcastle University

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/CC/D4CC00268G

Reference34 articles.

1. Recent Advances in Catalytic Asymmetric Construction of Atropisomers

2. Revealing Atropisomer Axial Chirality in Drug Discovery

3. Stereoselective construction of atropisomers featuring a C–N chiral axis

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1. Investigating quantum coherence of N-methylpyrrole through vibrational spectroscopy and potential energy: A theoretical study;Chemical Physics Letters;2024-09

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