Quantitative syntheses of permethylated closo-1,10-R2C2B8Me8 (R = H, Me) carboranes. Egg-shaped hydrocarbons on the Frontier between inorganic and organic chemistry-Reference-Cited by-同舟云学术

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Quantitative syntheses of permethylated closo-1,10-R2C2B8Me8 (R = H, Me) carboranes. Egg-shaped hydrocarbons on the Frontier between inorganic and organic chemistry

Published:2018 Issue:67 Volume:8 Page:38238-38244
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Bakardjiev Mario¹²³,Tok Oleg L.¹²³,Růžička Aleš⁴⁵⁶⁷³^ORCID,Růžičková Zdeňka⁴⁵⁶⁷³,Holub Josef¹²³,Hnyk Drahomír¹²³^ORCID,Fanfrlík Jindřich⁸³^ORCID,Štíbr Bohumil¹²³^ORCID

Affiliation:

1. Institute of Inorganic Chemistry

2. Academy of Sciences of the Czech Republic

3. Czech Republic

4. Department of General and Inorganic Chemistry

5. Faculty of Chemical Technology

6. University of Pardubice

7. 532 10 Pardubice

8. Institute of Organic Chemistry and Biochemistry of the Czech Academy of Sciences

Abstract

Reported are procedures leading to highly stable egg-shaped hydrocarbons with inner closo-1,10-C₂B₈ carborane core inside the methyl sheath.

Funder

Grantová Agentura České Republiky

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2018/RA/C8RA06640J

Reference26 articles.

1. For review, see: R. N.Grimes , Carboranes , Academic Press , 3rd edn, 2016

2. Representative derivative chemistry of the 1,6- and 1,10-B8C2H10 carborane system

3. Iron(II)- and manganese(I)-carborane complexes formed through metal-carbon .sigma. bonds

4. Metal−Metal Communication through Carborane Cages Supporting Electroactive [η5-CpFe(CO)2] Substituents

5. A silyl carborane containing the closo-1,10-C2B8H8 fragment

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1. Ten-vertex closo-carboranes react with “wet” fluoride: A direct closo-to-arachno transformation as a result of a hydride transfer;Inorganica Chimica Acta;2022-08

2. Thiaborane Icosahedral Barrier Increased by the Functionalization of all Terminal Hydrogens in closo-1-SB11H11;Inorganic Chemistry;2021-06-08

3. Electrophilic Methylation of Decaborane(14): Selective Synthesis of Tetramethylated and Heptamethylated Decaboranes and Their Conjugated Bases;Inorganic Chemistry;2020-07-14

4. Swollen Polyhedral Volume of the anti-B18H22 Cluster via Extensive Methylation: anti-B18H8Cl2Me12;Inorganic Chemistry;2020-02-11

5. Thiaboranes on Both Sides of the Icosahedral Barrier: Retaining and Breaking the Barrier with Carbon Functionalities;ChemPlusChem;2019-06-11

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