A multifunctional phosphite-containing electrolyte for 5 V-class LiNi0.5Mn1.5O4 cathodes with superior electrochemical performance-Reference-Cited by-同舟云学术

A multifunctional phosphite-containing electrolyte for 5 V-class LiNi0.5Mn1.5O4 cathodes with superior electrochemical performance

Published:2014 Issue:25 Volume:2 Page:9506-9513
ISSN:2050-7488
Container-title:J. Mater. Chem. A
language:en
Short-container-title:J. Mater. Chem. A

Author:

Song Young-Min¹²³,Han Jung-Gu¹²³,Park Soojin¹²³,Lee Kyu Tae¹²³,Choi Nam-Soon¹²³

Affiliation:

1. School of Green Energy

2. Ulsan National Institute of Science and Technology (UNIST)

3. Ulsan 689-798, Republic of Korea

Abstract

An organic–inorganic based surface film was formed on a 5 V-class LiNi_0.5Mn_1.5O₄ cathode by tris(trimethylsilyl)phosphite (TMSP). This surface-modified cathode exhibited significantly improved electrochemical properties in terms of cycling stability and rate capability.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2014/TA/C4TA01129E

Reference34 articles.

1. Challenges Facing Lithium Batteries and Electrical Double-Layer Capacitors

2. Nonaqueous Liquid Electrolytes for Lithium-Based Rechargeable Batteries

3. Electrolyte Reactions with the Surface of High Voltage LiNi[sub 0.5]Mn[sub 1.5]O[sub 4] Cathodes for Lithium-Ion Batteries

4. Mitigation of the irreversible capacity and electrolyte decomposition in a LiNi0.5Mn1.5O4/nano-TiO2 Li-ion battery

5. Fabrication and characterization of Li–Mn–Ni–O sputtered thin film high voltage cathodes for Li-ion batteries

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