Unusual differences in the reactivity of glutamic and aspartic acid in oxidative decarboxylation reactions

Author:

But Andrada1234,van der Wijst Evie1234,Le Nôtre Jérôme1234,Wever Ron5674,Sanders Johan P. M.1234,Bitter Johannes H.1234,Scott Elinor L.1234ORCID

Affiliation:

1. Chair of Biobased Chemistry and Technology

2. Wageningen University

3. 6700AA Wageningen

4. The Netherlands

5. Van't Hoff Institute for Molecular Sciences

6. University of Amsterdam

7. 1090 GD Amsterdam

Abstract

Chemically similar acidic amino acids present remarkable differences in reactivity under oxidative decarboxylation conditions for the production of biobased nitriles.

Funder

Wageningen University and Research Centre

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Environmental Chemistry

Reference40 articles.

1. J. W. A. Langeveld , J. P. M.Sanders and M. J. G.Meeusen, The Biobased Economy: Biofuels, Materials and Chemicals in the Post-oil Era, Earthscan, 2010

2. H. J. Arpe , Industrial Organic Chemistry, WILEY-VCH Verlag GmbH & Co. KGaA, 5th edn, 2012

3. Availability of protein-derived amino acids as feedstock for the production of bio-based chemicals

4. Biobased synthesis of acrylonitrile from glutamic acid

5. Synthesis of Biobased Succinonitrile from Glutamic Acid and Glutamine

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